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MEOR — Microbial Enhanced Oil Recovery

The MEOR process developed and tested by MicroPro GmbH over a period of 20 years is a highly effective tertiary oil production process on a micro­bio­lo­gical basis. This technology by reduction of water-cut leads to a revita­lization of oil production in depleting reser­voirs. It enables an enhanced production of oil through the injection of molasses and trillions of selected and adapted bacteria. The injected micro­or­ga­nisms grow on molasses, proli­ferate and synthesize various products (gases, acids, alcohols, surfac­tants) deep inside the reservoir.

For case-specific treat­ments at high tempe­rature and salinity MicroPro GmbH provides a compre­hensive culture collection of MEOR-bacteria.

The MEOR process includes a number oft production enhancing effects:

  • Bacterial gases increase reservoir pressure up to 20 bar and lead to a higher energy potential deep in the oil field
  • Organic acids build up new flow channels for oil by dissolving carbonate rock
  • Biolipids increase wettability and break up oil/water barriers

Due to the above processes fresh sections of the matrix which are not quite drained will be pulled into the oil extra­ction and increased pressure and permea­bility and therefore push signi­ficant amounts of trapped normally unreco­verable oil toward the production well. Per ton of molasses injected into the reservoir ~ 50 bbl MEOR-oil can be produced. Hence, on top of a water-flooding treatment an additional production of 10 – 15% of the Original Oil in Place (OOIP) has been recorded.

MEOR results are:

  • Reduction of water-cut by 15 – 30 %
  • Incre­asing production rate of stimu­lated producers by up to 50 %
  • Enhanced oil production by up to 150 %

 The costs for treatment amount, according to case-specific complexity, to a few USD per bbl additional oil.

Technology

MEOR – Technology

For MEOR treatment of oil reser­voirs previously selected bacteria are bred in fermenters on site and injected into the under­ground formation together with a molasses media. MEOR can be applied as a cyclic (“huff and puff”) or as a conti­nuous flooding process. Together with injection water selected micro­or­ga­nisms are injected deep into the reservoir, where they multiply and ferment the intro­duced nutrients (molasses).

Deep inside the reservoir trillions of micro­or­ga­nisms generate a number of production incre­asing substances, which lead to reduction of water cut and a signi­fi­cantly increased crude oil production rate.

Bacterial products and their impact on oil production:

Bacterial gases

Microbial productseffectsOil field parameters
CO2 (80 %), H2 (20 %) up to 380 mL per gram oft molassesIncrease of pressure up to 20 bar in model experienceIncrease of energy potential in the oil field
CH4 as final product from organic acids, alcohol’s and hydrogenIncrease of oil volume factor and therefore decrease of oil viscosityIncrease of oil mobilization
Change of pressure potential in fissures and poresIncrease of oil production rate

Organic acids

Microbial productseffectsOil field parameters
Essig‑, Propion‑, Butter- und Valerian-SäureDecrease of pH down to 4.8 Increase of rock permeability
Dissolving of carbo­natic rock by ~0.2 ton per ton molassesExtension of oil production to fresh not yet drained rock
Build up of new flow channels

Alcohols, biolipids

Microbial productseffectsOil field parameters
Methanol, ethanol, propanol, butanolDecrease of inter-factional tension (for example against heptane down to 12 — 46,5 mNm-1)Force imbibition of injected, fermented molasses media into pore canals and fissures to give more oil from the rock
biolipids Alteration of rock wettabilityBreak up of oil/water barriers and creating emulsions, Improve of flow rate

Effects of the MEOR-technology have been proven in numerous studies and applications:

  • Increase of energy potential inside the reservoir
  • Impro­vement of pressure potential in fissures and pores
  • Decrease of oil viscosity
  • Reduction of oil/water surface tension
  • Impro­vement of capillary adsorption of liquids
  • Increase of permea­bility by rock dissolution

In numerous tests and field appli­cation the oil production could be enhanced by more than 100 %.

Minimizing the risks

For a successful appli­cation of the MEOR technology we strongly recommend field-specific preli­minary inves­ti­ga­tions. This involves the evaluation of reservoir parameters and analysis of formation waters. More detailed prepa­ra­tions are carried only in case the reservoir is in principle suited for MEOR treatment.

A simulation of the MEOR process in model experi­ments on basis of original samples enables a reliable prognosis of antici­pated oil extra­ction rate and enhanced oil production. This reduces the economic risk level signi­fi­cantly before a field application.

A pilot test on a repre­sen­tative section of the reservoir with injection and production wells can provide us with concrete infor­mation about profi­ta­bility of the MEOR process within a short period of time.

MEOR – Step by step

Review of existing reservoir data

Evaluation of geologic and geophysical data

  • Evaluation of geologic and geophy­sical data 
    • Reservoir rock type, structure, thickness, porosity, permeability
    • Oil/water saturation
    • Mineral facies/ chemical composition
  • Fluid and gas characteristics 
    • Chemical compo­sition of oil, gas, water
    • Oil viscosity, density under reservoir conditions
    • Gas- oil; gas-water ratio, water cut
  • Deposit evaluation
    • OOIP — prognosis of deposit and single wells of interest, decline rate
  • Oil field configuration 
    • Number and positions of production and injection wells
    • Injection rates

Chemical and microbiological investigations

  • Existing bacterial population in oil field system:
  • Chemical compo­sition of reservoir water
  • Speci­fi­cation of adapt­ation program of MEOR bacteria to specific field conditions

Customization of MEOR to specific field conditions

  • Charac­te­rization and selection of MEOR microbes
  • Adaption of selected microbes to field conditions
  • Optimization of nutrient media
  • Analysis of bio-products with original sample material
  • Process engineering — scale up

Economic and technical evaluation of MEOR under simulated field conditions

  • Core flooding tests under reservoir condi­tions to simulate the MEOR drainage

MILESTONE:  Decision about application of MEOR process

Design and construction of MEOR station

MEOR treatment with continues process control

Case studies

MEOR – Case studies

Basically the MEOR process is appli­cable at all reservoir types, if the physical and chemical condi­tions for bacterial growth are met.

The MEOR process is parti­cu­larly suitable for carbonate deposits, repre­senting ~ 50 % of oil reser­voirs worldwide. Here some EOR-technologies, usually applied in sands (e.g. polymer‑, surfactant- and alkaline-flooding) show low efficiency because of chemical reactions. The parti­cular advan­tages of the MEOR technology with molasses in carbonate forma­tions are:

  • Injected bacteria spread wider and more quickly through fissures, fractures and pure canals
  • Reactions of generated bio-products take place deep inside the reservoir
  • Plugging of oil bearing strata by filtration, adsorption and on-growth of bacteria is minimized
  • Carbo­nates neutralize generated organic acids, which inten­sifies the formation of microbial products
  • New, not yet drained sections of reservoir rock are included in recovery as a result of microbial rock solution

The following case studies illus­trate the diverse and positive effects of MEOR treatment.

MEOR — Publications

  • Wagner, M., et.al. (1995) Develo­pment and Appli­cation of a New Biotech­nology of Molasses in-situ Method — Detailed Evaluation for Selected Wells in Romaschkino Carbonate Reservoir
    5th MEOR Confe­rence, Dallas, Texas 9
  • Wagner, M. et.al.: Verfahren und Anlage zur Herstellung von Impfgut für eine verbes­serte Erdöl­för­derung
    P 4307334, 24.04.1995
  • Wagner, M. (1994) Microbial Improved Oil Recovery
    Oil and Gas Technology, 3
  • Muslimov, R. et.al. Wagner, M. (1993) Microbial Improved Oil Recovery in Carbonate Reser­voirs — Prepa­ration of a Pilot Project in the Oil Field Romaschkino, Republic of Tartarstan
    7th European IOR Symposium, Moskau
  • Wagner, M. et.al. (1993) Micro­bially Improved Oil Recovery from Carbonate Reser­voirs
    Procee­dings Inter­na­tional Biohy­dro­me­tallurgy Symposium, Jackson Hole, Wyoming, USA
  • Wagner, M. et.al.: Verfahren zur Unter­drü­ckung sulfat­re­du­zie­render Bakterien bei MIOR
    DE 41 27 744 A1, 25.02.1993
  • Wagner, M. (1991) Microbial Enhancement of Oil Recovery from Carbonate Reser­voirs with Complex Formation Charac­te­ristics
    Procee­dings of the 1990 int. Conf. On Microbial Enhancement of Oil Recovery, Develo­p­ments in Petroleum Science 31 Elsevier
  • Wagner, M. et.al.: Stimulierungs- und Inten­si­vie­rungs­ver­fahren zur Gewinnung von Kohlen­was­ser­stoffen
    DL PS 277 297, 28.03.1990
  • Wagner, M. et.al.: Verfahren zur mikro­biellen Sekun­där­ge­winnung von Erdölen
    DL PS 2007 515, 08.06.1983